Bis(2,2′-bi-1H-imidazole-κ2N3,N3′)bis(dimethyl sulfoxide-κO)copper(II) bis(tetrafluoridoborate)
نویسندگان
چکیده
منابع مشابه
Bis(2,2′-bi-1H-imidazole-κ2 N 3,N 3′)bis(dimethyl sulfoxide-κO)copper(II) bis(tetrafluoridoborate)
In the title copper(II) salt, [Cu(C(6)H(6)N(4))(2)(C(2)H(6)OS)(2)](BF(4))(2), the Jahn-Teller distorted octa-hedral coordination sphere of copper is formed from four 2,2'-bi-1H-imidazole N atoms and two dimethyl sulfoxide O atoms. The Cu atom lies on a center of inversion. N-H⋯O and N-H⋯F hydrogen bonds give rise to a one-dimensional structure. The BF(4) (-) anion is disordered over two sites i...
متن کامل3,3′-(2,2′-Bi-1H-imidazole-1,1′-diyl)dipropanamide
In the title compound, C(12)H(16)N(6)O(2), the two imidazole rings are coplanar as a center of inversion exists midway along the C-C bond joining the two rings. In the crystal, inter-molecular N-H⋯O, N-H⋯N and C-H⋯O hydrogen bonds link adjacent mol-ecules into a two-dimensional layer structure parallel to (001).
متن کاملDiaquabis(2,2′-bi-1H-imidazole)manganese(II) benzene-1,4-dicarboxylate
The asymmetric unit of the title compound, [Mn(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(4)O(4)), contains one-half each of the centrosymmetric cation and anion. The Mn(II) atom is coordinated by four N atoms [Mn-N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2'-biimidazole ligands and two water mol-ecules [Mn-O = 2.2521 (14) Å] in a distorted octa-hedral geometry. Inter-molecular N-H⋯O and O-H⋯O hydrog...
متن کامل3,3′-(2,2′-Bi-1H-imidazole-1,1′-diyl)dipropanol
In the title compound, C(12)H(18)N(4)O(2), unlike other unconjugated disubstituted biimidazole derivatives reported so far, the two imidazole rings in a trans conformation exhibit a large planar rotation angle of 51.27 (4)°, and consist of half-mol-ecule asymmetric units related by a twofold rotation. The mol-ecules are linked into a three-dimensional framework with a parallel laminated constru...
متن کامل3,3′-(2,2′-Bi-1H-imidazole-1,1′-diyl)dipropanamide. Corrigendum
The list of authors in the paper by Zhi, Long, Chen & Ren [Acta Cryst. (2009), E65, o2008] is corrected and the acknowledgements are updated.[This corrects the article DOI: 10.1107/S1600536809028955.].
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810031922